網頁2015年10月19日 · A variety of approaches are used to suppress the contribution of phonons (lattice vibrations) to the thermal conductivity, including nanostructuring, … 網頁2014年1月15日 · The nature of the stereochemically active lone pair has long been a matter for debate. Here, by application of our recently developed orbital selective external potential (OSEP) method, we have studied the microscopic mechanism of stereochemically active lone pairs in various compounds. The OSEP met …
S-p Mixing in Stereochemically Active Lone Pairs Drives the …
網頁recently developed orbital selective external potential (OSEP) method, we have studied the microscopic mechanism of stereochemically active lone pairs in various compounds. … 網頁2024年4月13日 · Very recently, it has been reported that the quaternary sulfide CuPbBi 5 S 9 exhibits ultralow thermal conductivity, κ ≈ 0.5 W m –1 K –1, and can reach ZT = 0.43 at 700 K upon doping. (31,32) This material is a member (x = 2/3) of the bismuthinite-aikinite series, Cu 1–x x Pb 1–x Bi 1+x S 3 (0 ≤ x ≤ 1), all of which exhibit closely related crystal … proximity shock collar
Microscopic origin of stereochemically active lone pair formation …
網頁2013年12月12日 · The nature of the stereochemically active lone pair has long been a matter for debate. Here, by application of our recently developed orbital selective external potential (OSEP) method, we have studied the microscopic mechanism of stereochemically active lone pairs in various compounds. 網頁2024年9月30日 · Stereochemically active electron lone pairs from p-block cations can bring about pronounced structural distortions and give rise to electronic states that lie high in the valence band, where they are available for interactions with surface-adsorbed or intercalated species. , , , , In this study, we probe the electronic structure of FeSb 2 O 4 … 網頁2024年2月1日 · A so-called “Orbital Selective External Potential” (OSEP) method is used to quantitatively move 3d orbital energy levels and thus determine the main contribution of … rest hills hotel